This dataset includes Level 1B (L1B) and Level 2 (L2) data products from the MODIS/ASTER Airborne Simulator (MASTER) instrument. The spectral data were collected as part of the Hyperspectral Infrared Imager (HyspIRI) airborne campaign during 12 flights aboard a NASA ER-2 aircraft over Hawaii and southern California, U.S., from 2018-01-11 to 2018-02-20. This campaign includes imagery of Hawaii's volcanoes. Data products include L1B georeferenced multispectral imagery of calibrated radiance in 50 bands covering wavelengths of 0.460 to 12.879 micrometers at approximately 50-meter spatial resolution. Derived L2 data products are emissivity in 5 bands in thermal infrared range (8.58 to 12.13 micrometers) and land surface temperature. The L1B file format is HDF-4, and L2 products are provided in ENVI and KMZ formats. In addition, the dataset includes the flight path, spectral band information, instrument configuration, ancillary notes, and summary information for each flight, and browse images derived from each L1B data file.